Search results for "Inactive phase"

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Dynamical phase transitions and their relation to structural and thermodynamic aspects of glass physics.

2020

We review recent developments in structural–dynamical phase transitions in trajectory space based on dynamic facilitation theory. An open question is how the dynamic facilitation perspective on the glass transition may be reconciled with thermodynamic theories that posit collective reorganization accompanied by a growing static length scale and, eventually, a vanishing configurational entropy. In contrast, dynamic facilitation theory invokes a dynamical phase transition between an active phase (close to the normal liquid) and an inactive phase, which is glassy and whose order parameter is either a time-averaged dynamic or structural quantity. In particular, the dynamical phase transition in…

Length scalePhysicsPhase transition010304 chemical physicsConfiguration entropyCrossoverGeneral Physics and Astronomy010402 general chemistry01 natural sciences0104 chemical sciencesInactive phaseCriticalityCritical point (thermodynamics)0103 physical sciencesStatistical physicsPhysical and Theoretical ChemistryGlass transitionThe Journal of chemical physics
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